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ΔU is used rather than ΔG as a measure of the tendency of a dyeing process to occur because….
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The affinity of a particular dye on a given fibre will with increasing temperature for an immersion dyeing process. This is because of the TΔS term in the thermodynamic expression of a dye/fibre system becoming less as the temperature
The equation -ΔU = RT ln [D]f/[D]s could be used to calculate the standard affinity for a dye/fibre system showing an adsorption mechanism according this type of isotherm
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